Ultrathin Fe Films Sandwiched between Au Layers: CEMS- study
DOI:
https://doi.org/10.59992/IJSR.2023.v2n9p1Keywords:
Sandwich Structures, Magnetically Coupled Layers, Multilayered Systems, Monoatomic SuperlatticesAbstract
The STM studies of Fe films with thickness above 0.6 ML do not contribute significantly to the solution of the structural problems, because of the Au surface layer, which hinders details of the Fe sub-surface layers. The Mossbauer spectroscopy appears in this case as an exceptional method, which has the ability to solve structural and magnetic problems. Our discussion is based on a simplified spectrum analysis, assuming a discrete character of the spectral components. In reality, a distribution of the hyperfine magnetic field, as well as isomer shift and the quadrupole splitting is an obvious and natural consequence of the finite size system 'presented by the monolayer film. The exact fitting of all hyperfine parameters distribution is too difficult. Most of the fitting procedures treat the distributions of IS vs. Bhf and QS vs. Bhf as linearly dependent as described using the well-known Voigt-based method.
References
1. Rancourt, D. G., and J. Y. Ping. "Voigt-based distributions methods for arbitrary-shape in Mössbauer spectroscopy static hyperfine parameter." Nucl. Instrum. Methods Phys. Res. B 58 (1991): 85-97.
2. Suwa, Tomomi, Satoshi Tomita, Nobuyoshi Hosoito, and Hisao Yanagi. "Magnetic properties of fibonacci-modulated Fe-Au multilayer metamaterials." Materials 10, no. 10 (2017): 1209.
3. Takahashi, Y., T. Miyamachi, S. Nakashima, N. Kawamura, Y. Takagi, M. Uozumi, V. N. Antonov, T. Yokoyama, A. Ernst, and F. Komori. "Thickness-dependent electronic and magnetic properties of γ′− Fe 4 N atomic layers on Cu (001)." Physical Review B 95, no. 22 (2017): 224417
4. Muratov, Cyrill B., and Valeriy V. Slastikov. "Domain structure of ultrathin ferromagnetic elements in the presence of Dzyaloshinskii–Moriya interaction." Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 473, no. 2197 (2017): 20160666.
5. Yuan, Jiangtan, Andrew Balk, Hua Guo, Qiyi Fang, Sahil Patel, Xuanhan Zhao, Tanguy Terlier, Douglas Natelson, Scott Crooker, and Jun Lou. "Room-temperature magnetic order in air-stable ultrathin iron oxide." Nano letters 19, no. 6 (2019): 3777-3781.
6. An, Li, Jianrui Feng, Yu Zhang, Yong-Qing Zhao, Rui Si, Gui-Chang Wang, Fangyi Cheng, Pinxian Xi, and Shouheng Sun. "Controllable tuning of Fe-N nanosheets by Co substitution for enhanced oxygen evolution reaction." Nano Energy 57 (2019): 644-652
7. Martel, Laura, Amir Hen, Yo Tokunaga, François Kinnart, Nicola Magnani, Eric Colineau, Jean-Christophe Griveau, and Roberto Caciuffo. "Magnetization, specific heat, O 17 NMR, and Np 237 Mössbauer study of U 0.15 N p 0.85 O 2." Physical Review B 98, no. 1 (2018): 014410.
8. Mitsui, T., S. Sakai, S. Li, T. Ueno, T. Watanuki, Y. Kobayashi, R. Masuda, M. Seto, and H. Akai. "Magnetic Friedel Oscillation at the Fe (001) Surface: Direct Observation by Atomic-Layer-Resolved Synchrotron Radiation Fe 57 Mössbauer Spectroscopy." Physical Review Letters 125, no. 23 (2020): 236806.
9. Li, Chun, A. J. Freeman, and C. L. Fu. "Monolayer magnetism: electronic and magnetic properties of Fe/Au (001)." Journal of magnetism and magnetic materials 75, no. 3 (1988): 201-208.
10. Guo, G. Y., and H. Ebert. "First-principles studies of the magnetic hyperfine field in Fe multilayers." Hyperfine interactions 97, no. 1 (1996): 11-18.
11. Ślęzak, M., T. Ślęzak, K. Freindl, W. Karaś, N. Spiridis, M. Zając, A. I. Chumakov, S. Stankov, R. Rüffer, and J. Korecki. "Perpendicular magnetic anisotropy and noncollinear magnetic structure in ultrathin Fe films on W (110)." Physical Review B 87, no. 13 (2013): 134411.
12. Kiss, L. F., J. Balogh, L. Bujdosó, and D. Kaptás. "Magnetic properties of Fe-Ag multilayers with varying layer thickness and bilayer number." Physical Review B 98, no. 14 (2018): 144423.
13. Le Caër, G., and J. M. Dubois. "Evaluation of hyperfine parameter distributions from overlapped Mossbauer spectra of amorphous alloys." Journal of Physics E: Scientific Instruments 12, no. 11 (1979): 1083.
14. Okabayashi, Jun, Songtian Li, Seiji Sakai, Yasuhiro Kobayashi, Takaya Mitsui, Kiyohisa Tanaka, Yoshio Miura, and Seiji Mitani. "Perpendicular magnetic anisotropy at the Fe/Au (111) interface studied by Mössbauer, x-ray absorption, and photoemission spectroscopies." Physical Review B 103, no. 10 (2021): 104435.
15. Mössbauer Spectroscopy and its Applications, T E Cranshaw, B W Dale, G O Longworth and C E Johnson, (Cambridge Univ. Press: Cambridge) 1985.
16. Mössbauer Spectroscopy, D P E Dickson and F J Berry, (Cambridge Univ. Press, 1986.
17. The Mössbauer Effect, H Frauenfelder, (Benjamin: New York) 1962.
18. Principles of Mössbauer Spectroscopy, T C Gibb, (Chapman and Hall: London) 1977.
19. Mössbauer Spectroscopy, N N Greenwood and T C Gibb, (Chapman and Hall: Novel Materials and Ground States London), 1971.
20. Chemical Applications of Mössbauer Spectroscopy, V I Goldanskii and R H Herber ed., (Academic Press Inc: London) 1968.
21. Mössbauer Spectroscopy Applied to Inorganic Chemistry Vols. 1-3, G J Long, ed., (Plenum: New York) 1984-1989.
22. 21. Mössbauer Spectroscopy Applied to Magnetism and Materials Science Vol. 1, G J Long and F Grandjean, eds., (Plenum: New York) 1993.